Information card for entry 4122600

Structure parameters

• Formula: C14 H38 Co P2 Si2
• Calculated formula: C14 H38 Co P2 Si2
• SMILES: C([Si](C)(C)C)[Co]1(C[Si](C)(C)C)[P](C)(C)CC[P]1(C)C
• Title of publication: Bis(phosphine)cobalt dialkyl complexes for directed catalytic alkene hydrogenation.
• Authors of publication: Friedfeld, Max R.; Margulieux, Grant W.; Schaefer, Brian A.; Chirik, Paul J.
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2014
• Journal volume: 136
• Journal issue: 38
• Pages of publication: 13178 - 13181
• a: 16.251 ± 0.0014 Å
• b: 10.3659 ± 0.0009 Å
• c: 12.8209 ± 0.0011 Å
• α: 90°
• β: 92.811 ± 0.002°
• γ: 90°
• Cell volume: 2157.2 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0234
• Residual factor for significantly intense reflections: 0.0206
• Weighted residual factors for significantly intense reflections: 0.0589
• Weighted residual factors for all reflections included in the refinement: 0.0729
• Goodness-of-fit parameter for all reflections included in the refinement: 1.228
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No