A retro diels-alder route to diphosphorus chemistry: molecular precursor synthesis, kinetics of p2 transfer to 1,3-dienes, and detection of p2 by molecular beam mass spectrometry.
Authors of publication
Velian, Alexandra; Nava, Matthew; Temprado, Manuel; Zhou, Yan; Field, Robert W.; Cummins, Christopher C.
Journal of publication
Journal of the American Chemical Society
Year of publication
2014
Journal volume
136
Journal issue
39
Pages of publication
13586 - 13589
a
8.3108 ± 0.0009 Å
b
6.1042 ± 0.0007 Å
c
11.6311 ± 0.0013 Å
α
90°
β
108.656 ± 0.002°
γ
90°
Cell volume
559.05 ± 0.11 Å3
Cell temperature
100 ± 2 K
Ambient diffraction temperature
100 ± 2 K
Number of distinct elements
4
Space group number
4
Hermann-Mauguin space group symbol
P 1 21 1
Hall space group symbol
P 2yb
Residual factor for all reflections
0.0299
Residual factor for significantly intense reflections
0.0286
Weighted residual factors for significantly intense reflections
0.0765
Weighted residual factors for all reflections included in the refinement
0.0773
Goodness-of-fit parameter for all reflections included in the refinement
