Information card for entry 4122667

Structure parameters

• Formula: C30 H29 N Si
• Calculated formula: C30 H29 N Si
• SMILES: [Si](C1N(CCC1)/C=C/c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Structures and Reactivities of 2-Trityl- and 2-(Triphenylsilyl)pyrrolidine-Derived Enamines: Evidence for Negative Hyperconjugation with the Trityl Group.
• Authors of publication: Erdmann, Hannes; An, Feng; Mayer, Peter; Ofial, Armin R.; Lakhdar, Sami; Mayr, Herbert
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2014
• Journal volume: 136
• Journal issue: 40
• Pages of publication: 14263
• a: 9.8402 ± 0.0004 Å
• b: 8.4762 ± 0.0004 Å
• c: 28.5374 ± 0.0012 Å
• α: 90°
• β: 92.7937 ± 0.0012°
• γ: 90°
• Cell volume: 2377.4 ± 0.18 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0421
• Residual factor for significantly intense reflections: 0.0348
• Weighted residual factors for significantly intense reflections: 0.0878
• Weighted residual factors for all reflections included in the refinement: 0.0926
• Goodness-of-fit parameter for all reflections included in the refinement: 1.06
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No