Information card for entry 4123826

Structure parameters

• Formula: C8 H20 Au2 Cl2 O P2
• Calculated formula: C8 H20 Au2 Cl2 O P2
• SMILES: [Au](Cl)[P](O[P]([Au]Cl)(CC)CC)(CC)CC
• Title of publication: Air-Stable Gold Nanoparticles Ligated by Secondary Phosphine Oxides as Catalyst for the Chemoselective Hydrogenation of Substituted Aldehydes: a Remarkable Ligand Effect.
• Authors of publication: Cano, Israel; Huertos, Miguel A.; Chapman, Andrew M.; Buntkowsky, Gerd; Gutmann, Torsten; Groszewicz, Pedro B.; van Leeuwen, Piet W. N. M.
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2015
• Journal volume: 137
• Journal issue: 24
• Pages of publication: 7718 - 7727
• a: 10.5018 ± 0.0005 Å
• b: 11.2362 ± 0.0005 Å
• c: 13.3464 ± 0.0006 Å
• α: 90°
• β: 103.031 ± 0.001°
• γ: 90°
• Cell volume: 1534.32 ± 0.12 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0331
• Residual factor for significantly intense reflections: 0.0245
• Weighted residual factors for significantly intense reflections: 0.0492
• Weighted residual factors for all reflections included in the refinement: 0.0517
• Goodness-of-fit parameter for all reflections included in the refinement: 1.007
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No