Information card for entry 4124371

Structure parameters

• Formula: C27 H49 N O2 Si4 W
• Calculated formula: C27 H49 N O2 Si4 W
• Title of publication: Unexpected Formation of NHC-Stabilized Hydrosilylyne Complexes via Alkane Elimination from NHC-Stabilized Hydrido(alkylsilylene) Complexes.
• Authors of publication: Fukuda, Tetsuya; Hashimoto, Hisako; Tobita, Hiromi
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2015
• Journal volume: 137
• Journal issue: 34
• Pages of publication: 10906 - 10909
• a: 9.2153 ± 0.0009 Å
• b: 22.349 ± 0.002 Å
• c: 16.4645 ± 0.0016 Å
• α: 90°
• β: 100.491 ± 0.007°
• γ: 90°
• Cell volume: 3334.2 ± 0.6 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0313
• Residual factor for significantly intense reflections: 0.025
• Weighted residual factors for significantly intense reflections: 0.0468
• Weighted residual factors for all reflections included in the refinement: 0.0484
• Goodness-of-fit parameter for all reflections included in the refinement: 1.122
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No