Information card for entry 4124832

Structure parameters

• Chemical name: bromo-dimethyl-(C,N,N'-(2-(((2-(dimethylamino)ethyl)(methyl)amino)methyl)phenyl)platinum
• Formula: C14 H25 Br N2 Pt
• Calculated formula: C14 H25 Br N2 Pt
• SMILES: [Pt]12(Br)([N](Cc3c2cccc3)(C)CC[N]1(C)C)(C)C
• Title of publication: Exclusive Csp(3)-Csp(3) vs Csp(2)-Csp(3) Reductive Elimination from Pt(IV) Governed by Ligand Constraints.
• Authors of publication: Bowes, Eric G.; Pal, Shrinwantu; Love, Jennifer A.
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2015
• Journal volume: 137
• Journal issue: 51
• Pages of publication: 16004 - 16007
• a: 7.3874 ± 0.0014 Å
• b: 8.2772 ± 0.0016 Å
• c: 13.402 ± 0.003 Å
• α: 94.032 ± 0.004°
• β: 101.952 ± 0.005°
• γ: 103.382 ± 0.005°
• Cell volume: 773.9 ± 0.3 ų
• Cell temperature: 90 K
• Ambient diffraction temperature: 90 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0233
• Residual factor for significantly intense reflections: 0.021
• Weighted residual factors for significantly intense reflections: 0.0493
• Weighted residual factors for all reflections included in the refinement: 0.0502
• Goodness-of-fit parameter for all reflections included in the refinement: 1.037
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No