Syntheses of (+)-30-epi-, (-)-6-epi-, (±)-6,30-epi-13,14-Didehydroxyisogarcinol and (±)-6,30-epi-Garcimultiflorone A Utilizing Highly Diastereoselective, Lewis Acid-Controlled Cyclizations.
Authors of publication
Boyce, Jonathan H.; Eschenbrenner-Lux, Vincent; Porco, Jr, John A
Journal of publication
Journal of the American Chemical Society
Year of publication
2016
Journal volume
138
Journal issue
44
Pages of publication
14789 - 14797
a
10.9732 ± 0.001 Å
b
16.0101 ± 0.0014 Å
c
15.5863 ± 0.0014 Å
α
90°
β
94.993 ± 0.003°
γ
90°
Cell volume
2727.8 ± 0.4 Å3
Cell temperature
100 ± 2 K
Ambient diffraction temperature
100 ± 2 K
Number of distinct elements
3
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/n 1
Hall space group symbol
-P 2yn
Residual factor for all reflections
0.0389
Residual factor for significantly intense reflections
0.0386
Weighted residual factors for significantly intense reflections
0.0952
Weighted residual factors for all reflections included in the refinement
0.0955
Goodness-of-fit parameter for all reflections included in the refinement
