Information card for entry 4125713

Structure parameters

• Formula: C25 H52 Co N4 Si4
• Calculated formula: C25 H52 Co N4 Si4
• SMILES: [Co](N([Si](C)(C)C)[Si](C)(C)C)(N([Si](C)(C)C)[Si](C)(C)C)=C1N(C=CN1c1c(cc(cc1C)C)C)C
• Title of publication: Mode of Activation of Cobalt(II) Amides for Catalytic Hydrosilylation of Alkenes with Tertiary Silanes.
• Authors of publication: Liu, Yang; Deng, Liang
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2017
• Journal volume: 139
• Journal issue: 5
• Pages of publication: 1798 - 1801
• a: 8.8549 ± 0.0009 Å
• b: 10.1984 ± 0.001 Å
• c: 20.531 ± 0.002 Å
• α: 81.077 ± 0.002°
• β: 86.856 ± 0.002°
• γ: 66.166 ± 0.002°
• Cell volume: 1675.4 ± 0.3 ų
• Cell temperature: 130 K
• Ambient diffraction temperature: 130 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0566
• Residual factor for significantly intense reflections: 0.0368
• Weighted residual factors for significantly intense reflections: 0.0847
• Weighted residual factors for all reflections included in the refinement: 0.0926
• Goodness-of-fit parameter for all reflections included in the refinement: 1.038
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No