Information card for entry 4126692

Structure parameters

• Formula: C197 H252 N12 S8 Si4
• Calculated formula: C197 H252 N12 S8 Si4
• Title of publication: Facile Conversion of Bis-Silylene to Cyclic Silylene Isomers: Unexpected C-N and C-H Bond Cleavage.
• Authors of publication: Wang, Yuzhong; Hickox, Hunter P.; Xie, Yaoming; Wei, Pingrong; Schaefer, Henry F.; Robinson, Gregory H.
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2017
• a: 54.583 ± 0.004 Å
• b: 14.563 ± 0.0012 Å
• c: 25.285 ± 0.002 Å
• α: 90°
• β: 110.778 ± 0.002°
• γ: 90°
• Cell volume: 18792 ± 3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.1544
• Residual factor for significantly intense reflections: 0.0997
• Weighted residual factors for significantly intense reflections: 0.2247
• Weighted residual factors for all reflections included in the refinement: 0.2499
• Goodness-of-fit parameter for all reflections included in the refinement: 1.094
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No