Information card for entry 4127206

Structure parameters

• Formula: C30 H52 N2 Ru Si4
• Calculated formula: C30 H52 N2 Ru Si4
• SMILES: C(#[N]C(C)(C)C)[RuH2]12([Si](c3c(cccc3)[Si]1(C)C)(C)C)(C#[N]C(C)(C)C)[Si](c1ccccc1[Si]2(C)C)(C)C
• Title of publication: Disilaruthena- and ferra-cyclic complexes containing isocyanide lig-ands as effective catalysts for hydrogenation of unfunctionalized ste-rically hindered alkenes.
• Authors of publication: Sunada, Yusuke; Ogushi, Hajime; Yamamoto, Taiji; Uto, Shoko; Sawano, Mina; Tahara, Atsushi; Tanaka, Hiromasa; Shiota, Yoshihito; Yoshizawa, Kazunari; Nagashima, Hideo
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2018
• a: 9.5868 ± 0.0016 Å
• b: 9.751 ± 0.002 Å
• c: 11.415 ± 0.003 Å
• α: 81.858 ± 0.015°
• β: 67.712 ± 0.013°
• γ: 62.781 ± 0.011°
• Cell volume: 877.4 ± 0.3 ų
• Cell temperature: 123 K
• Ambient diffraction temperature: 123 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.027
• Residual factor for significantly intense reflections: 0.0261
• Weighted residual factors for significantly intense reflections: 0.0604
• Weighted residual factors for all reflections included in the refinement: 0.0609
• Goodness-of-fit parameter for all reflections included in the refinement: 1.074
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No