Activation of C-H, N-H, and O-H Bonds via Proton-Coupled Electron Transfer to a Mn(III) Complex of Redox-Noninnocent Octaazacyclotetradecadiene, a Catenated-Nitrogen Macrocyclic Ligand.
Authors of publication
Vaddypally, Shivaiah; Tomlinson, Warren; O'Sullivan, Owen T; Ding, Ran; Van Vliet, Megan M.; Wayland, Bradford B.; Hooper, Joseph P.; Zdilla, Michael J.
Journal of publication
Journal of the American Chemical Society
Year of publication
2019
Journal volume
141
Journal issue
14
Pages of publication
5699 - 5709
a
17.504 ± 0.002 Å
b
18.005 ± 0.002 Å
c
17.337 ± 0.002 Å
α
90°
β
113.955 ± 0.002°
γ
90°
Cell volume
4993.3 ± 1 Å3
Cell temperature
100 ± 2 K
Ambient diffraction temperature
99.98 K
Number of distinct elements
5
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/c 1
Hall space group symbol
-P 2ybc
Residual factor for all reflections
0.0675
Residual factor for significantly intense reflections
0.0454
Weighted residual factors for significantly intense reflections
0.1085
Weighted residual factors for all reflections included in the refinement
0.1173
Goodness-of-fit parameter for all reflections included in the refinement
