Information card for entry 4129425

Structure parameters

• Common name: ALM-VIII-19
• Formula: C31 H23 F10 N O5 Si
• Calculated formula: C31 H23 F10 N O5 Si
• SMILES: c12c(c(c(c(c1O[Si]1(O2)(Oc2c(c(c(c(c2O1)F)F)F)F)OC(c1ccccc1)N(C(C)C)C(C)C)F)F)F)F.c1(c(cccc1)F)F
• Title of publication: Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilylation Catalyzed by a Neutral Silicon Compound.
• Authors of publication: Liberman-Martin, Allegra L; Bergman, Robert G.; Tilley, T. Don
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2015
• Journal volume: 137
• Journal issue: 16
• Pages of publication: 5328 - 5331
• a: 33.591 ± 0.002 Å
• b: 13.3628 ± 0.0008 Å
• c: 14.0068 ± 0.0008 Å
• α: 90°
• β: 106.444 ± 0.002°
• γ: 90°
• Cell volume: 6030.1 ± 0.6 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0491
• Residual factor for significantly intense reflections: 0.0466
• Weighted residual factors for significantly intense reflections: 0.1317
• Weighted residual factors for all reflections included in the refinement: 0.1342
• Goodness-of-fit parameter for all reflections included in the refinement: 1.032
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: cukα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No