Selective C-H Activation at a Molecular Rhodium Sigma-Alkane Complex by Solid/Gas Single-Crystal to Single-Crystal H/D Exchange.
Authors of publication
Chadwick, F. Mark; Krämer, Tobias; Gutmann, Torsten; Rees, Nicholas H.; Thompson, Amber L.; Edwards, Alison J.; Buntkowsky, Gerd; Macgregor, Stuart A.; Weller, Andrew S.
Journal of publication
Journal of the American Chemical Society
Year of publication
2016
Journal volume
138
Journal issue
40
Pages of publication
13369 - 13378
a
19.1 ± 0.002 Å
b
18.289 ± 0.0009 Å
c
27.926 ± 0.003 Å
α
90°
β
134.55 ± 0.02°
γ
90°
Cell volume
6952 ± 3 Å3
Cell temperature
290 K
Ambient diffraction temperature
290 K
Number of distinct elements
6
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/c 1
Hall space group symbol
-P 2ybc
Residual factor for all reflections
0.0776
Residual factor for significantly intense reflections
0.0637
Weighted residual factors for all reflections
0.1879
Weighted residual factors for significantly intense reflections
0.1632
Weighted residual factors for all reflections included in the refinement
0.1876
Goodness-of-fit parameter for all reflections included in the refinement
