Information card for entry 4131480

Structure parameters

• Formula: C82 H61 B F24 N O4 P2 Rh
• Calculated formula: C82 H61 B F24 N O4 P2 Rh
• Title of publication: Exploiting Carbonyl Groups to Control Intermolecular Rhodium-Catalyzed Alkene and Alkyne Hydroacylation.
• Authors of publication: Coxon, Thomas J.; Fernández, Maitane; Barwick-Silk, James; McKay, Alasdair I.; Britton, Louisa E.; Weller, Andrew S.; Willis, Michael C.
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2017
• Journal volume: 139
• Journal issue: 29
• Pages of publication: 10142 - 10149
• a: 12.8242 ± 0.0002 Å
• b: 16.9411 ± 0.0003 Å
• c: 19.1569 ± 0.0003 Å
• α: 76.451 ± 0.001°
• β: 83.436 ± 0.001°
• γ: 69.514 ± 0.001°
• Cell volume: 3787.85 ± 0.11 ų
• Cell temperature: 150.01 ± 0.1 K
• Ambient diffraction temperature: 150.01 ± 0.1 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0284
• Residual factor for significantly intense reflections: 0.0272
• Weighted residual factors for significantly intense reflections: 0.0701
• Weighted residual factors for all reflections included in the refinement: 0.0713
• Goodness-of-fit parameter for all reflections included in the refinement: 1.017
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No