Information card for entry 4131738

Structure parameters

• Chemical name: tris(tris(dimethylsilyl)methyl)cerium
• Formula: C21 H63 Ce Si9
• Calculated formula: C21 H63 Ce Si9
• SMILES: [Ce](C([SiH](C)C)([SiH](C)C)[SiH](C)C)(C([SiH](C)C)([SiH](C)C)[SiH](C)C)C([SiH](C)C)([SiH](C)C)[SiH](C)C
• Title of publication: Homoleptic Trivalent Tris(alkyl) Rare Earth Compounds.
• Authors of publication: Pindwal, Aradhana; Yan, KaKing; Patnaik, Smita; Schmidt, Bradley M.; Ellern, Arkady; Slowing, Igor I.; Bae, Cheolbeom; Sadow, Aaron D.
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2017
• Journal volume: 139
• Journal issue: 46
• Pages of publication: 16862 - 16874
• a: 11.5041 ± 0.001 Å
• b: 11.5417 ± 0.001 Å
• c: 16.7043 ± 0.0015 Å
• α: 100.352 ± 0.0015°
• β: 98.519 ± 0.0015°
• γ: 114.706 ± 0.0014°
• Cell volume: 1919.3 ± 0.3 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0419
• Residual factor for significantly intense reflections: 0.0304
• Weighted residual factors for significantly intense reflections: 0.0744
• Weighted residual factors for all reflections included in the refinement: 0.0829
• Goodness-of-fit parameter for all reflections included in the refinement: 0.786
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No