Information card for entry 4132108

Structure parameters

• Formula: C15 H18 O2 Si
• Calculated formula: C15 H18 O2 Si
• SMILES: [Si](O)(O)(c1ccccc1)[C@@H](C)Cc1ccccc1
• Title of publication: Iron-Catalyzed Highly Enantioselective Hydrosilylation of Unactivated Terminal Alkenes.
• Authors of publication: Cheng, Biao; Liu, Wenbo; Lu, Zhan
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2018
• Journal volume: 140
• Journal issue: 15
• Pages of publication: 5014 - 5017
• a: 19.379 ± 0.004 Å
• b: 5.3296 ± 0.0005 Å
• c: 15.117 ± 0.003 Å
• α: 90°
• β: 111.02 ± 0.02°
• γ: 90°
• Cell volume: 1457.4 ± 0.5 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293.15 K
• Number of distinct elements: 4
• Space group number: 5
• Hermann-Mauguin space group symbol: C 1 2 1
• Hall space group symbol: C 2y
• Residual factor for all reflections: 0.1107
• Residual factor for significantly intense reflections: 0.1014
• Weighted residual factors for significantly intense reflections: 0.2625
• Weighted residual factors for all reflections included in the refinement: 0.2829
• Goodness-of-fit parameter for all reflections included in the refinement: 1.18
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No