Information card for entry 4133073

Structure parameters

• Chemical name: bis(mu2-2,2,2',2'-tetramethyl-1,3-benzenedipropanoato-O,O')-aqua-rhodium- bismuth
• Formula: C32 H41.44 Bi O9 Rh
• Calculated formula: C32 H41.4366 Bi O9 Rh
• Title of publication: Enhanced Electrophilicity of Heterobimetallic Bi-Rh Paddlewheel Carbene Complexes: A Combined Experimental, Spectroscopic, and Computational Study.
• Authors of publication: Collins, Lee R.; van Gastel, Maurice; Neese, Frank; Fürstner, Alois
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2018
• Journal volume: 140
• Journal issue: 40
• Pages of publication: 13042 - 13055
• a: 6.5384 ± 0.0007 Å
• b: 19.201 ± 0.002 Å
• c: 12.6755 ± 0.0014 Å
• α: 90°
• β: 92.199 ± 0.002°
• γ: 90°
• Cell volume: 1590.2 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 7
• Hermann-Mauguin space group symbol: P 1 c 1
• Hall space group symbol: P -2yc
• Residual factor for all reflections: 0.0476
• Residual factor for significantly intense reflections: 0.0418
• Weighted residual factors for significantly intense reflections: 0.0872
• Weighted residual factors for all reflections included in the refinement: 0.0887
• Goodness-of-fit parameter for all reflections included in the refinement: 1.223
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: Mo-Kα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No