Information card for entry 4133157

Structure parameters

• Formula: C26 H29 N Si
• Calculated formula: C26 H29 N Si
• SMILES: [Si@]1(c2cc(ccc2N2C[C@H](C[C@H]1C2)Cc1ccccc1)C)(c1ccccc1)C.[Si@@]1(c2cc(ccc2N2C[C@@H](C[C@@H]1C2)Cc1ccccc1)C)(c1ccccc1)C
• Title of publication: Catalytic Access to Bridged Sila- N-heterocycles from Piperidines via Cascade sp³ and sp² C-Si Bond Formation.
• Authors of publication: Zhang, Jianbo; Park, Sehoon; Chang, Sukbok
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2018
• Journal volume: 140
• Journal issue: 41
• Pages of publication: 13209 - 13213
• a: 8.6064 ± 0.0012 Å
• b: 11.501 ± 0.0017 Å
• c: 12.8161 ± 0.0018 Å
• α: 71.48 ± 0.005°
• β: 71.156 ± 0.005°
• γ: 69.281 ± 0.005°
• Cell volume: 1092.9 ± 0.3 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.052
• Residual factor for significantly intense reflections: 0.0431
• Weighted residual factors for significantly intense reflections: 0.1184
• Weighted residual factors for all reflections included in the refinement: 0.126
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No