Information card for entry 4133608

Structure parameters

• Formula: C63 H74 B Ge N4 O Si2
• Calculated formula: C63 H75 B Ge N4 O Si2
• SMILES: [Ge]1[Si]2([N](=C(N2C(C)(C)C)c2ccccc2)C(C)(C)C)c2c3Oc4c([Si]51[N](=C(N5C(C)(C)C)c1ccccc1)C(C)(C)C)cccc4C(c3ccc2)(C)C.c1(ccccc1)[BH](c1ccccc1)c1ccccc1
• Title of publication: An Isolable Bis(silylene)-Stabilized Germylone and Its Reactivity.
• Authors of publication: Wang, Yuwen; Karni, Miriam; Yao, Shenglai; Apeloig, Yitzhak; Driess, Matthias
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2019
• Journal volume: 141
• Journal issue: 4
• Pages of publication: 1655 - 1664
• a: 9.0383 ± 0.0003 Å
• b: 18.6293 ± 0.0006 Å
• c: 18.9925 ± 0.0006 Å
• α: 112.389 ± 0.003°
• β: 91.666 ± 0.003°
• γ: 94.184 ± 0.003°
• Cell volume: 2943.35 ± 0.18 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0567
• Residual factor for significantly intense reflections: 0.0435
• Weighted residual factors for significantly intense reflections: 0.1132
• Weighted residual factors for all reflections included in the refinement: 0.1244
• Goodness-of-fit parameter for all reflections included in the refinement: 1.029
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No