Cyclic (amino)(aryl)carbenes (CAArCs) enter the field of chromophore ligands - Expanded π system leads to unusually deep red emitting Cu<sup>I</sup> compounds.
Authors of publication
Gernert, Markus; Balles-Wolf, Lukas; Kerner, Florian; M Uuml Ller, Ulrich; Schmiedel, Alexander; Holzapfel, Marco; Marian, Christel M.; Pflaum, Jens; Lambert, Christoph; Steffen, Andreas
Journal of publication
Journal of the American Chemical Society
Year of publication
2020
a
14.765 ± 0.005 Å
b
16.931 ± 0.003 Å
c
22.655 ± 0.003 Å
α
90°
β
90°
γ
90°
Cell volume
5663 ± 2 Å3
Cell temperature
100 ± 2 K
Ambient diffraction temperature
100 ± 2 K
Number of distinct elements
4
Space group number
61
Hermann-Mauguin space group symbol
P b c a
Hall space group symbol
-P 2ac 2ab
Residual factor for all reflections
0.0399
Residual factor for significantly intense reflections
0.0303
Weighted residual factors for significantly intense reflections
0.0805
Weighted residual factors for all reflections included in the refinement
0.0859
Goodness-of-fit parameter for all reflections included in the refinement
