Information card for entry 4134939

Structure parameters

• Formula: C76 H190 Gd2 K2 N8 O19 Si12
• Calculated formula: C76 H190 Gd2 K2 N8 O19 Si12
• Title of publication: Formation of the End-on Bound Lanthanide Dinitrogen Complexes, [(R2N)3Ln-N=N-Ln(NR2)3]2-, from Divalent [(R2N)3Ln]1- Salts (R = SiMe3).
• Authors of publication: Ryan, Austin J.; Balasubramani, Sreeganesh; Ziller, Joseph W.; Furche, Filipp; Evans, William J.
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2020
• a: 15.658 ± 0.003 Å
• b: 16.014 ± 0.003 Å
• c: 24.347 ± 0.004 Å
• α: 78.975 ± 0.002°
• β: 77.363 ± 0.002°
• γ: 82.456 ± 0.003°
• Cell volume: 5821.6 ± 1.8 ų
• Cell temperature: 88 ± 2 K
• Ambient diffraction temperature: 88 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0739
• Residual factor for significantly intense reflections: 0.0465
• Weighted residual factors for significantly intense reflections: 0.1014
• Weighted residual factors for all reflections included in the refinement: 0.1129
• Goodness-of-fit parameter for all reflections included in the refinement: 1.041
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No