Information card for entry 4135102

Structure parameters

• Formula: C23 H21 N O2 Si
• Calculated formula: C23 H21 N O2 Si
• Title of publication: Enantioselective Diarylcarbene Insertion into Si-H Bonds Induced by Electronic Properties of the Carbenes.
• Authors of publication: Yang, Liang-Liang; Evans, Declan; Xu, Bin; Li, Wen-Tao; Li, Mao-Lin; Zhu, Shou-Fei; Houk, K. N.; Zhou, Qi-Lin
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2020
• a: 9.952 ± 0.002 Å
• b: 19.926 ± 0.004 Å
• c: 10.453 ± 0.002 Å
• α: 90°
• β: 90.6 ± 0.03°
• γ: 90°
• Cell volume: 2072.8 ± 0.7 ų
• Cell temperature: 113 ± 2 K
• Ambient diffraction temperature: 113.15 K
• Number of distinct elements: 5
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.0912
• Residual factor for significantly intense reflections: 0.0763
• Weighted residual factors for significantly intense reflections: 0.1955
• Weighted residual factors for all reflections included in the refinement: 0.2095
• Goodness-of-fit parameter for all reflections included in the refinement: 1.078
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No