Difunctionalization of C-C σ-Bonds Enabled by the Reaction of Bicyclo[1.1.0]butyl Boronate Complexes with Electrophiles: Reaction Development, Scope, and Stereochemical Origins.
Authors of publication
Bennett, Steven H.; Fawcett, Alexander; Denton, Elliott H.; Biberger, Tobias; Fasano, Valerio; Winter, Nils; Aggarwal, Varinder K.
Journal of publication
Journal of the American Chemical Society
Year of publication
2020
Journal volume
142
Journal issue
39
Pages of publication
16766 - 16775
a
6.2461 ± 0.0002 Å
b
6.9103 ± 0.0002 Å
c
22.7041 ± 0.0006 Å
α
90°
β
94.1036 ± 0.0016°
γ
90°
Cell volume
977.45 ± 0.05 Å3
Cell temperature
100 ± 2 K
Ambient diffraction temperature
100 ± 2 K
Number of distinct elements
4
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/c 1
Hall space group symbol
-P 2ybc
Residual factor for all reflections
0.0341
Residual factor for significantly intense reflections
0.0305
Weighted residual factors for significantly intense reflections
0.0816
Weighted residual factors for all reflections included in the refinement
0.0839
Goodness-of-fit parameter for all reflections included in the refinement
