Information card for entry 4302977

Structure parameters

• Formula: C65 H89 N4 Ni P4 Si
• Calculated formula: C65 H89 N4 Ni P4 Si
• Title of publication: Side-on Coordination of a P-P Bond in Heterobinuclear Tetraphosphorus Complexes with a [Si(μ,η2:2-P4)Ni] Core and Nickel(I) Centers
• Authors of publication: Yun Xiong; Shenglai Yao; Eckhard Bill; Matthias Driess
• Journal of publication: Inorganic Chemistry
• Year of publication: 2009
• Journal volume: 48
• Pages of publication: 7522 - 7524
• a: 21.8775 ± 0.0014 Å
• b: 12.1597 ± 0.0006 Å
• c: 24.278 ± 0.0014 Å
• α: 90°
• β: 106.187 ± 0.006°
• γ: 90°
• Cell volume: 6202.5 ± 0.6 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1308
• Residual factor for significantly intense reflections: 0.0565
• Weighted residual factors for significantly intense reflections: 0.1239
• Weighted residual factors for all reflections included in the refinement: 0.1397
• Goodness-of-fit parameter for all reflections included in the refinement: 0.919
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No