Information card for entry 4304461

Structure parameters

• Formula: C36 H31 N2 P3
• Calculated formula: C36 H31 N2 P3
• SMILES: P(N(P(c1ccccc1)c1ccccc1)NP(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Migratory Insertion of the R2P Group into a Nitrogen-Nitrogen Bond - A Novel Type of Rearrangement in Phosphorus-Nitrogen Ligand Chemistry. 3. The Rearrangement of Triphosphinohydrazide Ligand -N(PPh2)-N(PPh2)2 to Triphosphazenide Anion {[(Ph2P-N]2PPh2}- in the Coordination Sphere of Divalent Cobalt and Nickel
• Authors of publication: Vyacheslav V. Sushev; Natalia V. Belina; Georgy K. Fukin; Yuriy A. Kurskiy; Alexander N. Kornev; Gleb A. Abakumov
• Journal of publication: Inorganic Chemistry
• Year of publication: 2008
• Journal volume: 47
• Pages of publication: 2608 - 2612
• a: 14.9713 ± 0.001 Å
• b: 9.5166 ± 0.0006 Å
• c: 21.9221 ± 0.0015 Å
• α: 90°
• β: 103.129 ± 0.001°
• γ: 90°
• Cell volume: 3041.7 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0659
• Residual factor for significantly intense reflections: 0.0492
• Weighted residual factors for significantly intense reflections: 0.1208
• Weighted residual factors for all reflections included in the refinement: 0.1309
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No