Information card for entry 4304877

Structure parameters

• Common name: [Au{C(NHCH3)2}2]AsF6
• Formula: C6 H16 As Au F6 N4
• Calculated formula: C6 H16 As Au F6 N4
• SMILES: CNC(NC)=[Au]=C(NC)NC.[F-][As](F)(F)(F)(F)F
• Title of publication: Blue or Green Glowing Crystals of the Cation [Au{C(NHMe)2}2]+. Structural Effects of Anions, Hydrogen Bonding, and Solvate Molecules on the Luminescence of a Two-Coordinate Gold(I) Carbene Complex
• Authors of publication: Daniel Rios; David M. Pham; James C. Fettinger; Marilyn M. Olmstead; Alan L. Balch
• Journal of publication: Inorganic Chemistry
• Year of publication: 2008
• Journal volume: 47
• Pages of publication: 3442 - 3451
• a: 20.1461 ± 0.0017 Å
• b: 6.6955 ± 0.0006 Å
• c: 10.2929 ± 0.0009 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 1388.4 ± 0.2 ų
• Cell temperature: 90 ± 2 K
• Ambient diffraction temperature: 90 ± 2 K
• Number of distinct elements: 6
• Space group number: 62
• Hermann-Mauguin space group symbol: P n m a
• Hall space group symbol: -P 2ac 2n
• Residual factor for all reflections: 0.0201
• Residual factor for significantly intense reflections: 0.0169
• Weighted residual factors for significantly intense reflections: 0.0407
• Weighted residual factors for all reflections included in the refinement: 0.0418
• Goodness-of-fit parameter for all reflections included in the refinement: 1.13
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No