Information card for entry 4305191

Structure parameters

• Chemical name: [Pt2Ag2(PP3)2Cl5]Cl.CHCl3.H2O
• Formula: C85 H84 Ag2 Cl9 O P8 Pt2
• Calculated formula: C85 H84 Ag2 Cl9 O P8 Pt2
• SMILES: ClC(Cl)Cl.O.[Pt]12([P](CC[P]2(c2ccccc2)c2ccccc2)(CC[P]1(c1ccccc1)c1ccccc1)CC[P](c1ccccc1)(c1ccccc1)[Ag]1([Cl][Ag]([Cl]1)[P](CC[P]12[Pt]([P](c3ccccc3)(CC1)c1ccccc1)([P](CC2)(c1ccccc1)c1ccccc1)Cl)(c1ccccc1)c1ccccc1)Cl)Cl.[Cl-]
• Title of publication: Novel Chelate Ring-Opening Induced by Silver(I) of Five-Coordinate Palladium(II) and Platinum(II) Complexes Containing Tripodal Polyphosphines
• Authors of publication: D. Fernández-Anca; M. Inés García-Seijo; Alfonso Castiñeiras; M. Esther García-Fernández
• Journal of publication: Inorganic Chemistry
• Year of publication: 2008
• Journal volume: 47
• Pages of publication: 5685 - 5695
• a: 16.144 ± 0.005 Å
• b: 18.459 ± 0.006 Å
• c: 18.548 ± 0.006 Å
• α: 65.977 ± 0.005°
• β: 81.592 ± 0.005°
• γ: 77.054 ± 0.005°
• Cell volume: 4911 ± 3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1023
• Residual factor for significantly intense reflections: 0.0619
• Weighted residual factors for significantly intense reflections: 0.1994
• Weighted residual factors for all reflections included in the refinement: 0.223
• Goodness-of-fit parameter for all reflections included in the refinement: 1.126
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No