Information card for entry 4306709

Structure parameters

• Chemical name: N-(trifluoromethylsulfonatodimethylsilyl)-N-[bis-(2,4,6-trimethylphenyl)phenyl] amino-chloromethylarsane toluene solvate
• Formula: C28 H34 As Cl F3 N O3 S Si
• Calculated formula: C28 H34 As Cl F3 N O3 S Si
• SMILES: [As](Cl)(N([Si](OS(=O)(=O)C(F)(F)F)(C)C)c1c(cccc1c1c(cc(cc1C)C)C)c1c(cc(cc1C)C)C)C
• Title of publication: Lewis-Acid-Assisted Methyl Exchange Reactions In Silylated Aminodichloroarsanes
• Authors of publication: Dirk Michalik; Axel Schulz; Alexander Villinger
• Journal of publication: Inorganic Chemistry
• Year of publication: 2008
• Journal volume: 47
• Pages of publication: 11798 - 11806
• a: 8.51 ± 0.0017 Å
• b: 12.946 ± 0.003 Å
• c: 28.447 ± 0.006 Å
• α: 90°
• β: 95.7 ± 0.03°
• γ: 90°
• Cell volume: 3118.5 ± 1.2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 9
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0518
• Residual factor for significantly intense reflections: 0.0363
• Weighted residual factors for significantly intense reflections: 0.0873
• Weighted residual factors for all reflections included in the refinement: 0.0919
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No