Information card for entry 4306852

Structure parameters

• Formula: C38 H24 Co11 N4 O26 Rh
• Calculated formula: C38 H12 Co10.564 N4 O26 Rh1.436
• Title of publication: Mixed Co-Rh Nitrido-Encapsulated Carbonyl Clusters. Synthesis, Solid-State Structure, and Electrochemical/EPR Characterization of the Anions [Co10Rh(N)2(CO)21]3-, [Co10Rh2(N)2(CO)24]2-, and [Co11Rh(N)2(CO)24]2-
• Authors of publication: Michela Costa; Roberto Della Pergola; Alessandro Fumagalli; Franco Laschi; Serena Losi; Piero Macchi; Angelo Sironi; Piero Zanello
• Journal of publication: Inorganic Chemistry
• Year of publication: 2007
• Journal volume: 46
• Pages of publication: 552 - 560
• a: 23.608 ± 0.005 Å
• b: 11.054 ± 0.005 Å
• c: 22.55 ± 0.005 Å
• α: 90 ± 0.005°
• β: 109.74 ± 0.005°
• γ: 90 ± 0.005°
• Cell volume: 5539 ± 3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0362
• Residual factor for significantly intense reflections: 0.025
• Weighted residual factors for significantly intense reflections: 0.0716
• Weighted residual factors for all reflections included in the refinement: 0.0746
• Goodness-of-fit parameter for all reflections included in the refinement: 1.082
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No