Information card for entry 4307891

Structure parameters

• Formula: C30 H30 Cl4 N6 O V2
• Calculated formula: C30 H30 Cl4 N6 O V2
• SMILES: c1cccc[n]1[V]([n]1ccccc1)([n]1ccccc1)(O[V]([n]1ccccc1)([n]1ccccc1)([n]1ccccc1)(Cl)Cl)(Cl)Cl
• Title of publication: Reaction of p-Toluenesulfonylamide and M(NMe2)4 (M = Ti, V): Generation of Electron-Deficient Imido Complexes of Early Transition Metals
• Authors of publication: Christian Lorber; Robert Choukroun; Laure Vendier
• Journal of publication: Inorganic Chemistry
• Year of publication: 2007
• Journal volume: 46
• Pages of publication: 3192 - 3202
• a: 15.306 ± 0.003 Å
• b: 15.806 ± 0.003 Å
• c: 16.916 ± 0.003 Å
• α: 98.44 ± 0.03°
• β: 96.79 ± 0.03°
• γ: 98.97 ± 0.03°
• Cell volume: 3956.7 ± 1.4 ų
• Cell temperature: 180 K
• Ambient diffraction temperature: 180 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.3463
• Residual factor for significantly intense reflections: 0.1096
• Weighted residual factors for significantly intense reflections: 0.1953
• Weighted residual factors for all reflections included in the refinement: 0.2596
• Goodness-of-fit parameter for all reflections included in the refinement: 0.679
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No