Information card for entry 4308315

Structure parameters

• Formula: C18 H48 Al6 N6
• Calculated formula: C18 H48 Al6 N6
• Title of publication: Preparation and Characterization of Lithium Imidoalanate Complexes Li2[(RN)4(AlH2)6] (R = Me or tBu): First Examples of Aluminum-Rich Imidoalanes with an Adamantoid Structure
• Authors of publication: Christina Y. Tang; Andrew R. Cowley; Anthony J. Downs; Simon Parsons
• Journal of publication: Inorganic Chemistry
• Year of publication: 2007
• Journal volume: 46
• Pages of publication: 5439 - 5446
• a: 10.5708 ± 0.0002 Å
• b: 16.547 ± 0.0004 Å
• c: 17.0406 ± 0.0004 Å
• α: 92.1463 ± 0.0009°
• β: 93.8153 ± 0.0009°
• γ: 91.387 ± 0.0011°
• Cell volume: 2970.9 ± 0.11 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Sample thermal history: The material was crystallised at ambient temperature. A suitable crystal was cooled rapidly to 150K for single-crystal X-ray diffraction analysis.
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1078
• Residual factor for significantly intense reflections: 0.0405
• Weighted residual factors for all reflections: 0.097
• Weighted residual factors for significantly intense reflections: 0.0449
• Weighted residual factors for all reflections included in the refinement: 0.0449
• Goodness-of-fit parameter for all reflections included in the refinement: 1.0872
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No