Information card for entry 4308772

Structure parameters

• Formula: C43 H47 F6 N3 O2 P3 Rh
• Calculated formula: C43 H47 F6 N3 O2 P3 Rh
• SMILES: [RhH2]1([P](c2ccccc2)(c2ccccc2)c2ccccc2)([P](c2ccccc2)(c2ccccc2)c2ccccc2)[O]=C(N[N]1=C(C)C)N.[P](F)(F)(F)(F)(F)[F-].O=C(C)C
• Title of publication: Interactions of Rh(III)-Dihydrido-Bis(phosphine) Complexes with Semicarbazones
• Authors of publication: Maria B. Ezhova; Brian O. Patrick; Kapila N. Sereviratne; Brian R. James; Francis J. Waller; Michael E. Ford
• Journal of publication: Inorganic Chemistry
• Year of publication: 2005
• Journal volume: 44
• Pages of publication: 1482 - 1491
• a: 12.6183 ± 0.0009 Å
• b: 12.7951 ± 0.0005 Å
• c: 14.244 ± 0.001 Å
• α: 79.465 ± 0.002°
• β: 73.471 ± 0.002°
• γ: 83.606 ± 0.003°
• Cell volume: 2163.2 ± 0.2 ų
• Cell temperature: 173.2 K
• Ambient diffraction temperature: 173.2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.056
• Residual factor for significantly intense reflections: 0.032
• Weighted residual factors for all reflections: 0.089
• Weighted residual factors for all reflections included in the refinement: 0.089
• Goodness-of-fit parameter for all reflections: 1.131
• Goodness-of-fit parameter for all reflections included in the refinement: 1.131
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No