Information card for entry 4308808

Structure parameters

• Formula: C48 H106 B11 P2 Rh
• Calculated formula: C46 H96 B12 P2 Rh
• Title of publication: Dihydrogen Complexes of Rhodium: [RhH2(H2)x(PR3)2]+ (R = Cy,iPr; x= 1, 2)
• Authors of publication: Michael J. Ingleson; Simon K. Brayshaw; Mary F. Mahon; Giuseppe D. Ruggiero; Andrew S. Weller
• Journal of publication: Inorganic Chemistry
• Year of publication: 2005
• Journal volume: 44
• Pages of publication: 3162 - 3171
• a: 15.132 ± 0.0004 Å
• b: 17.842 ± 0.0004 Å
• c: 21.199 ± 0.0008 Å
• α: 90 ± 0.002°
• β: 90 ± 0.001°
• γ: 90 ± 0.001°
• Cell volume: 5723.4 ± 0.3 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 63
• Hermann-Mauguin space group symbol: C m c m
• Hall space group symbol: -C 2c 2
• Residual factor for all reflections: 0.2208
• Residual factor for significantly intense reflections: 0.1511
• Weighted residual factors for significantly intense reflections: 0.4626
• Weighted residual factors for all reflections included in the refinement: 0.492
• Goodness-of-fit parameter for all reflections included in the refinement: 1.807
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No