Information card for entry 4309095

Structure parameters

• Common name: (m-2,2bpym)[Cu(AsPh3)2]2(BF4)2
• Chemical name: [(m-2,2bipyrimidin)dicopper-bis-triphenylarsin]di-terafluoroborat
• Formula: C80 H70 As4 B2 Cu2 F8 N4 O2
• Calculated formula: C80 H70 As4 B2 Cu2 F8 N4 O0.578
• Title of publication: Geometrical and Electronic Structures of Dinuclear Complex Ions {(μ-bpym)[Cu(EAr3)2]2}2+ with Intramolecular "Organic Sandwich" Formation (E = P or As; Ar = Aryl; bpym = 2,2'-Bipyrimidine)
• Authors of publication: Monika Sieger; Conny Vogler; Axel Klein; Axel Knödler; Matthias Wanner; Jan Fiedler; Stanislav Záliš; Theo L. Snoeck; Wolfgang Kaim
• Journal of publication: Inorganic Chemistry
• Year of publication: 2005
• Journal volume: 44
• Pages of publication: 4637 - 4643
• a: 11.875 ± 0.002 Å
• b: 12.704 ± 0.003 Å
• c: 14.941 ± 0.003 Å
• α: 64.9 ± 0.03°
• β: 71.89 ± 0.03°
• γ: 74.6 ± 0.03°
• Cell volume: 1916.5 ± 0.9 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0905
• Residual factor for significantly intense reflections: 0.0525
• Weighted residual factors for significantly intense reflections: 0.109
• Weighted residual factors for all reflections included in the refinement: 0.1272
• Goodness-of-fit parameter for all reflections included in the refinement: 1.036
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No