Information card for entry 4309488

Structure parameters

• Common name: Mg-TMEDA-NHSi(iPr)3
• Formula: C24 H60 Mg N4 Si2
• Calculated formula: C24 H60 Mg N4 Si2
• SMILES: [Si](C(C)C)(C(C)C)(C(C)C)N[Mg]1(N[Si](C(C)C)(C(C)C)C(C)C)[N](C)(C)CC[N]1(C)C
• Title of publication: Ligand Exchange Reaction Between an Alkylzinc Primary Amide and a Dialkylmagnesium Compound: Crystal Structures of [(thf)MeMg-μ-N(H)SiiPr3]2 and (tmeda)Mg[N(H)SiiPr3]2
• Authors of publication: Matthias Westerhausen; Tobias Bollwein; Nikolaos Makropoulos; Holger Piotrowski
• Journal of publication: Inorganic Chemistry
• Year of publication: 2005
• Journal volume: 44
• Pages of publication: 6439 - 6444
• a: 15.93 ± 0.0012 Å
• b: 10.2952 ± 0.0006 Å
• c: 19.9613 ± 0.0015 Å
• α: 90°
• β: 102.449 ± 0.009°
• γ: 90°
• Cell volume: 3196.7 ± 0.4 ų
• Cell temperature: 200 ± 3 K
• Ambient diffraction temperature: 200 ± 3 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0638
• Residual factor for significantly intense reflections: 0.0461
• Weighted residual factors for significantly intense reflections: 0.1207
• Weighted residual factors for all reflections included in the refinement: 0.1282
• Goodness-of-fit parameter for all reflections included in the refinement: 1.02
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No