Information card for entry 4309873

Structure parameters

• Chemical name: Tetra(μ-chloro)tetracarbonylbis(μ-(1,3-di-tert -butyl-2,4-bis(2-methoxyethoxy)-[1,3,2,4] diazadiphosphetidine,κ,P;κ,P)tetrarhodium(I)
• Formula: C16 H32 Cl2 N2 O6 P2 Rh2
• Calculated formula: C16 H32 Cl2 N2 O6 P2 Rh2
• Title of publication: Cyclodiphosphazanes with Hemilabile Ponytails: Synthesis, Transition Metal Chemistry (Ru(II), Rh(I), Pd(II), Pt(II)), and Crystal and Molecular Structures of Mononuclear (Pd(II), Rh(I)) and Bi- and Tetranuclear Rhodium(I) Complexes
• Authors of publication: P. Chandrasekaran; Joel T. Mague; Maravanji S. Balakrishna
• Journal of publication: Inorganic Chemistry
• Year of publication: 2005
• Journal volume: 44
• Pages of publication: 7925 - 7932
• a: 9.339 ± 0.0009 Å
• b: 18.286 ± 0.002 Å
• c: 14.916 ± 0.001 Å
• α: 90°
• β: 99.753 ± 0.001°
• γ: 90°
• Cell volume: 2510.4 ± 0.4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0368
• Residual factor for significantly intense reflections: 0.032
• Weighted residual factors for significantly intense reflections: 0.0816
• Weighted residual factors for all reflections included in the refinement: 0.0839
• Goodness-of-fit parameter for all reflections included in the refinement: 1.095
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No