Information card for entry 4310199

Structure parameters

• Common name: Platinum gold Carbonyl Phosphine cluster
• Formula: C154 H120 Au4 O10 P8 Pt13
• Calculated formula: C154 H120 Au4 O10 P8 Pt13
• SMILES: C(#[O])[Pt]123456[Au]78([P](c9ccccc9)(c9ccccc9)c9ccccc9)[Au]9%10([P](c%11ccccc%11)(c%11ccccc%11)c%11ccccc%11)[Pt]%11%12%13%1417(C#[O])[Pt]17%15289(C#[O])[Pt]289%10%11(C#[O])[Pt]%10%11%16%17%13(C(=O)[Pt]%13%183%12%10([P](c3ccccc3)(c3ccccc3)c3ccccc3)[Pt]3%10%12%19%204%1412%11[Pt]124%11%14%21(C#[O])[Au]%22%23([P](c%24ccccc%24)(c%24ccccc%24)c%24ccccc%24)[Au]%241([P](c1ccccc1)(c1ccccc1)c1ccccc1)[Pt]1%16%1332%22(C#[O])[Pt]5%18%104%23(C#[O])[Pt]26%15%20%21(C(=O)[Pt]79%19%142([P](c2ccccc2)(c2ccccc2)c2ccccc2)[Pt]8%17%12%11%241C#[O])[P](c1ccccc1)(c1ccccc1)c1ccccc1)[P](c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Synthesis and Structural Analysis of the First Nanosized Platinum-Gold Carbonyl/Phosphine Cluster, Pt13[Au2(PPh3)2]2(CO)10(PPh3)4, Containing a Pt-Centered [Ph3PAu-AuPPh3]-Capped Icosahedral Pt12 Cage
• Authors of publication: Namal de Silva; Lawrence F. Dahl
• Journal of publication: Inorganic Chemistry
• Year of publication: 2005
• Journal volume: 44
• Pages of publication: 9604 - 9606
• a: 15.9017 ± 0.0016 Å
• b: 16.0409 ± 0.0016 Å
• c: 17.5928 ± 0.0018 Å
• α: 78.963 ± 0.002°
• β: 63.696 ± 0.001°
• γ: 63.132 ± 0.002°
• Cell volume: 3588.4 ± 0.6 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1518
• Residual factor for significantly intense reflections: 0.0733
• Weighted residual factors for significantly intense reflections: 0.163
• Weighted residual factors for all reflections included in the refinement: 0.2009
• Goodness-of-fit parameter for all reflections included in the refinement: 0.976
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No