Information card for entry 4311014

Structure parameters

• Common name: DM-TTF-(PPh2)2PtCl2, Tl(OTf), Et2O
• Formula: C37 H36 Cl2 F3 O4 P2 Pt S5 Tl
• Calculated formula: C37 H36 Cl2 F3 O4 P2 Pt S5 Tl
• Title of publication: Unexpected Reactivity of PdCl2 and PtCl2 Complexes of the Unsaturated Diphosphineo-Me2TTF(PPh2)2 toward Chloride Abstraction with Thallium Triflate
• Authors of publication: Thomas Devic; Patrick Batail; Marc Fourmigué; Narcis Avarvari
• Journal of publication: Inorganic Chemistry
• Year of publication: 2004
• Journal volume: 43
• Pages of publication: 3136 - 3141
• a: 10.0411 ± 0.0004 Å
• b: 18.958 ± 0.002 Å
• c: 23.73 ± 0.004 Å
• α: 90°
• β: 97.363 ± 0.005°
• γ: 90°
• Cell volume: 4480 ± 0.9 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 9
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.1131
• Residual factor for significantly intense reflections: 0.0493
• Weighted residual factors for significantly intense reflections: 0.096
• Weighted residual factors for all reflections included in the refinement: 0.1156
• Goodness-of-fit parameter for all reflections included in the refinement: 1.002
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No