Information card for entry 4311130

Structure parameters

• Formula: As2 Cd Rb4 S9
• Calculated formula: As2 Cd Rb4 S8.838
• Title of publication: [Mn2(AsS4)4]8- and [Cd2(AsS4)2(AsS5)2]8-: Discrete Clusters with High Negative Charge from Alkali Metal Polythioarsenate Fluxes
• Authors of publication: Ratnasabapathy G. Iyer; Mercouri G. Kanatzidis
• Journal of publication: Inorganic Chemistry
• Year of publication: 2004
• Journal volume: 43
• Pages of publication: 3656 - 3662
• a: 9.122 ± 0.002 Å
• b: 9.285 ± 0.002 Å
• c: 12.4 ± 0.003 Å
• α: 111.7 ± 0.006°
• β: 108.744 ± 0.005°
• γ: 90.163 ± 0.005°
• Cell volume: 915.2 ± 0.4 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0666
• Residual factor for significantly intense reflections: 0.0501
• Weighted residual factors for significantly intense reflections: 0.1123
• Weighted residual factors for all reflections included in the refinement: 0.119
• Goodness-of-fit parameter for all reflections included in the refinement: 1.05
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No