Information card for entry 4312056

Structure parameters

• Formula: C87 H99 Cl4 Ge N4
• Calculated formula: C87 H99 Cl4 Ge N4
• Title of publication: Divalent Germanium Compound with a Radical-Anionic Ligand: Molecular Structures of (dpp-BIAN).-GeCl and Its Hydrochloration Products [(dpp-BIAN)(H)2].+[GeCl3]- and [{(dpp-BIAN)(H)2.+}2(Cl-)]+[GeCl3]- (dpp-BIAN = 1,2-Bis{(2,6-diisopropylphenyl)imino}acenaphthene)
• Authors of publication: Igor L. Fedushkin; Natalie M. Khvoinova; Andrey Yu. Baurin; Georgii K. Fukin; Vladimir K. Cherkasov; Mikhail P. Bubnov
• Journal of publication: Inorganic Chemistry
• Year of publication: 2004
• Journal volume: 43
• Pages of publication: 7807 - 7815
• a: 21.3305 ± 0.0012 Å
• b: 15.6716 ± 0.0009 Å
• c: 24.0119 ± 0.0013 Å
• α: 90°
• β: 99.03 ± 0.001°
• γ: 90°
• Cell volume: 7927.3 ± 0.8 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0628
• Residual factor for significantly intense reflections: 0.0441
• Weighted residual factors for significantly intense reflections: 0.1067
• Weighted residual factors for all reflections included in the refinement: 0.1134
• Goodness-of-fit parameter for all reflections included in the refinement: 1.02
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No