Information card for entry 4313732

Structure parameters

• Formula: C14 H24 F6 K O6 P
• Calculated formula: C14 H24 F6 K O6 P
• SMILES: C([P-]C(F)(F)F)(F)(F)F.[K]12345[O]6CC[O]1CC[O]2CC[O]3CC[O]4CC[O]5CC[O]6
• Title of publication: Stabilization of the P(CF~3~)~2~^-^ and P(C~6~F~5~)~2~^-^ Ions by Coordination to Pentacarbonyl Tungsten: Structures of [18-crown-6-K]P(CF~3~)~2~, [18-crown-6-K][W{P(CF~3~)~2~}(CO)~5~] and [18-crown-6-K][{W(CO)~5~}~2~{μ-P(C~6~F~5~)~2~}].THF
• Authors of publication: Berthold Hoge; Christoph Thösen; Tobias Herrmann; Ingo Pantenburg
• Journal of publication: Inorganic Chemistry
• Year of publication: 2003
• Journal volume: 42
• Pages of publication: 3633 - 3641
• a: 16.335 ± 0.008 Å
• b: 9.641 ± 0.003 Å
• c: 13.702 ± 0.006 Å
• α: 90°
• β: 97.14 ± 0.04°
• γ: 90°
• Cell volume: 2141.1 ± 1.6 ų
• Cell temperature: 170 ± 2 K
• Ambient diffraction temperature: 170 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.1535
• Residual factor for significantly intense reflections: 0.0752
• Weighted residual factors for significantly intense reflections: 0.1428
• Weighted residual factors for all reflections included in the refinement: 0.1744
• Goodness-of-fit parameter for all reflections included in the refinement: 0.954
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No