Information card for entry 4313734

Structure parameters

• Formula: C19 H24 F6 K O11 P W
• Calculated formula: C19 H24 F6 K O11 P W
• SMILES: [W](P(C(F)(F)F)C(F)(F)F)(C#[O])(C#[O])(C#[O])(C#[O])C#[O].[K]12345[O]6CC[O]2CC[O]1CC[O]3CC[O]4CC[O]5CC6
• Title of publication: Stabilization of the P(CF~3~)~2~^-^ and P(C~6~F~5~)~2~^-^ Ions by Coordination to Pentacarbonyl Tungsten: Structures of [18-crown-6-K]P(CF~3~)~2~, [18-crown-6-K][W{P(CF~3~)~2~}(CO)~5~] and [18-crown-6-K][{W(CO)~5~}~2~{μ-P(C~6~F~5~)~2~}].THF
• Authors of publication: Berthold Hoge; Christoph Thösen; Tobias Herrmann; Ingo Pantenburg
• Journal of publication: Inorganic Chemistry
• Year of publication: 2003
• Journal volume: 42
• Pages of publication: 3633 - 3641
• a: 10.45 ± 0.002 Å
• b: 11.398 ± 0.002 Å
• c: 13.181 ± 0.003 Å
• α: 75.51 ± 0.02°
• β: 70.581 ± 0.014°
• γ: 88.301 ± 0.015°
• Cell volume: 1431.1 ± 0.5 ų
• Cell temperature: 170 ± 2 K
• Ambient diffraction temperature: 170 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0978
• Residual factor for significantly intense reflections: 0.0396
• Weighted residual factors for all reflections: 0.0679
• Weighted residual factors for significantly intense reflections: 0.0528
• Goodness-of-fit parameter for all reflections: 0.636
• Goodness-of-fit parameter for significantly intense reflections: 0.678
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No