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Information card for entry 4314103
Preview
Coordinates | 4314103.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C50 H40 N2 O2 Os P2 |
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Calculated formula | C50 H40 N2 O2 Os P2 |
SMILES | [Os]12([P](c3ccccc3)(c3ccccc3)c3ccccc3)([P](c3ccccc3)(c3ccccc3)c3ccccc3)(Oc3ccc(C)cc3[N]1=Nc1ccccc21)C#[O] |
Title of publication | Chemically Induced Cyclometalation of 2-(Arylazo)phenols. Synthesis, Characterization, and Redox Properties of a Family of Organoosmium Complexes |
Authors of publication | Parna Gupta; Ray J. Butcher; Samaresh Bhattacharya |
Journal of publication | Inorganic Chemistry |
Year of publication | 2003 |
Journal volume | 42 |
Pages of publication | 5405 - 5411 |
a | 12.262 ± 0.003 Å |
b | 19.353 ± 0.005 Å |
c | 18.41 ± 0.004 Å |
α | 90° |
β | 108.136 ± 0.016° |
γ | 90° |
Cell volume | 4151.8 ± 1.8 Å3 |
Cell temperature | 296 ± 2 K |
Ambient diffraction temperature | 296 ± 2 K |
Number of distinct elements | 6 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/c 1 |
Hall space group symbol | -P 2ybc |
Residual factor for all reflections | 0.0592 |
Residual factor for significantly intense reflections | 0.0354 |
Weighted residual factors for significantly intense reflections | 0.0745 |
Weighted residual factors for all reflections included in the refinement | 0.0829 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.02 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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