Information card for entry 4314285

Structure parameters

• Chemical name: Potassium(THF)2(16-crown-6)tetrakis(diphenylformamidinato)divanadium(I,II)
• Formula: C72 H84 K N8 O8 V2
• Calculated formula: C72 H68 K N8 O8 V2
• Title of publication: New Chemistry of the Triply Bonded Divanadium (V24+) Unit and Reduction to an Unprecedented V23+ Core
• Authors of publication: F. Albert Cotton; Elizabeth A. Hillard; Carlos A. Murillo; Xiaoping Wang
• Journal of publication: Inorganic Chemistry
• Year of publication: 2003
• Journal volume: 42
• Pages of publication: 6063 - 6070
• a: 12.4792 ± 0.0016 Å
• b: 12.5923 ± 0.0015 Å
• c: 13.3625 ± 0.0016 Å
• α: 65.337 ± 0.002°
• β: 65.078 ± 0.002°
• γ: 88.078 ± 0.002°
• Cell volume: 1704.6 ± 0.4 ų
• Cell temperature: 213 ± 2 K
• Ambient diffraction temperature: 213 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1082
• Residual factor for significantly intense reflections: 0.0889
• Weighted residual factors for significantly intense reflections: 0.1858
• Weighted residual factors for all reflections included in the refinement: 0.1987
• Goodness-of-fit parameter for all reflections included in the refinement: 1.049
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No