Information card for entry 4314292

Structure parameters

• Chemical name: tetrakis(THF)lithium-tris-3,5-dichlorophenylformamdinate vanadium(II)
• Formula: C55 H53 Cl12 Li N6 O4 V
• Calculated formula: C55 H53 Cl12 Li N6 O4 V
• Title of publication: New Chemistry of the Triply Bonded Divanadium (V24+) Unit and Reduction to an Unprecedented V23+ Core
• Authors of publication: F. Albert Cotton; Elizabeth A. Hillard; Carlos A. Murillo; Xiaoping Wang
• Journal of publication: Inorganic Chemistry
• Year of publication: 2003
• Journal volume: 42
• Pages of publication: 6063 - 6070
• a: 11.0014 ± 0.0007 Å
• b: 15.975 ± 0.001 Å
• c: 18.9046 ± 0.0012 Å
• α: 98.468 ± 0.001°
• β: 96.081 ± 0.001°
• γ: 105.737 ± 0.001°
• Cell volume: 3125.7 ± 0.3 ų
• Cell temperature: 213 ± 2 K
• Ambient diffraction temperature: 213 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0904
• Residual factor for significantly intense reflections: 0.0544
• Weighted residual factors for significantly intense reflections: 0.1338
• Weighted residual factors for all reflections included in the refinement: 0.1532
• Goodness-of-fit parameter for all reflections included in the refinement: 1.014
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No