Information card for entry 4315140

Structure parameters

• Formula: C38 H40 Co Mo N14 O8 Rb
• Calculated formula: C38 H34 Co Mo N14 O8 Rb
• Title of publication: Series of MI[Co(bpy)3][Mo(CN)8].nH2O (MI= Li (1), K (2), Rb (3), Cs (4); n= 7-8) Exhibiting Reversible Diamagnetic to Paramagnetic Transition Coupled with Dehydration-Rehydration Process
• Authors of publication: Marcin Kozieł; Robert Podgajny; Rafał Kania; Rémy Lebris; Corine Mathonière; Krzysztof Lewiński; Krzysztof Kruczała; Michał Rams; Christine Labrugère; Azzedine Bousseksou; Barbara Sieklucka
• Journal of publication: Inorganic Chemistry
• Year of publication: 2010
• Journal volume: 49
• Pages of publication: 2765 - 2772
• a: 16.639 ± 0.0003 Å
• b: 13.806 ± 0.0002 Å
• c: 19.451 ± 0.0003 Å
• α: 90°
• β: 107.218 ± 0.001°
• γ: 90°
• Cell volume: 4268 ± 0.12 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0543
• Residual factor for significantly intense reflections: 0.0373
• Weighted residual factors for significantly intense reflections: 0.0843
• Weighted residual factors for all reflections included in the refinement: 0.0895
• Goodness-of-fit parameter for all reflections included in the refinement: 1.048
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No