Information card for entry 4316815

Structure parameters

• Chemical name: Tetrachloro-bis(triphenylphosphine oxide) plutonium(iv)
• Formula: C36 H30 Cl4 O2 P2 Pu
• Calculated formula: C36 H30 Cl4 O2 P2 Pu
• SMILES: c1(ccccc1)P(c1ccccc1)(=[O][Pu](Cl)([O]=P(c1ccccc1)(c1ccccc1)c1ccccc1)(Cl)(Cl)Cl)c1ccccc1
• Title of publication: The Reaction Chemistry of Plutonyl(VI) Chloride Complexes with Triphenyl Phosphineoxide and Triphenyl Phosphinimine
• Authors of publication: Claude Berthon; Nathalie Boubals; Iraida A. Charushnikova; David Collison; Stéphanie M. Cornet; Christophe Den Auwer; Andrew J. Gaunt; Nikolas Kaltsoyannis; Iain May; Sebastien Petit; Michael P. Redmond; Sean D. Reilly; Brian L. Scott
• Journal of publication: Inorganic Chemistry
• Year of publication: 2010
• Journal volume: 49
• Pages of publication: 9554 - 9562
• a: 13.9751 ± 0.0009 Å
• b: 13.1612 ± 0.001 Å
• c: 20.2217 ± 0.0015 Å
• α: 90°
• β: 96.33 ± 0.004°
• γ: 90°
• Cell volume: 3696.7 ± 0.5 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.1081
• Residual factor for significantly intense reflections: 0.0479
• Weighted residual factors for significantly intense reflections: 0.0687
• Weighted residual factors for all reflections included in the refinement: 0.0801
• Goodness-of-fit parameter for all reflections included in the refinement: 0.884
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No