Information card for entry 4317697

Structure parameters

• Formula: C24 H14 Co2 N O7 P Ru Se
• Calculated formula: C24 H14 Co2 N O7 P Ru Se
• SMILES: [Ru]12([Co]34([Co]1([Se]23)([P](c1[n]4cccc1)(c1ccccc1)c1ccccc1)(C#[O])C#[O])(C#[O])C#[O])(C#[O])(C#[O])C#[O]
• Title of publication: Reactivity of the Heterometallic Clusters [HMCo3(CO)12] and [Et4N][MCo3(CO)12] (M = Fe, Ru) toward Phosphine Selenides, Including Selenium Transfer. Crystal Structures of [HRuCo3(CO)7(μ-CO)3(μ-dppy)], [MCo2(μ3-Se)(CO)7(μ-dppy)], and [RuCo2(μ3-Se)(CO)7(μ-dppm)] [dppy = Ph2(2-C5H4N)P, dppm = Ph2PCH2PPh2]
• Authors of publication: Pierre Braunstein; Claudia Graiff; Chiara Massera; Giovanni Predieri; Jacky Rosé; Antonio Tiripicchio
• Journal of publication: Inorganic Chemistry
• Year of publication: 2002
• Journal volume: 41
• Pages of publication: 1372 - 1382
• a: 12.148 ± 0.004 Å
• b: 21.466 ± 0.005 Å
• c: 11.4 ± 0.004 Å
• α: 90°
• β: 116.27 ± 0.06°
• γ: 90°
• Cell volume: 2666 ± 2 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1425
• Residual factor for significantly intense reflections: 0.0444
• Weighted residual factors for significantly intense reflections: 0.0809
• Weighted residual factors for all reflections included in the refinement: 0.1044
• Goodness-of-fit parameter for all reflections included in the refinement: 0.808
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No