Information card for entry 4317714

Structure parameters

• Formula: C38 H36 B F10 N10 O4 P Rh2
• Calculated formula: C38 H36 B F10 N10 O4 P Rh2
• SMILES: [Rh]123([Rh]4([n]5c(c6[n]4c4[n]2cccc4cc6)cccc5)([O]=C(O1)C)(OC(=[O]3)C)[N]#CC)([n]1c2nc(c3ccccn3)ccc2ccc1)[N]#CC.[B](F)(F)(F)[F-].[P](F)(F)(F)(F)(F)[F-].C(#N)C.N#CC
• Title of publication: Homologous Series of Redox-Active, Dinuclear Cations [M2(O2CCH3)2(pynp)2]2+ (M = Mo, Ru, Rh) with the Bridging Ligand 2-(2-Pyridyl)-1,8-naphthyridine (pynp)
• Authors of publication: Cristian Saul Campos-Fernández; Lisa M. Thomson; José Ramón Galán-Mascarós; Xiang Ouyang; Kim R. Dunbar
• Journal of publication: Inorganic Chemistry
• Year of publication: 2002
• Journal volume: 41
• Pages of publication: 1523 - 1533
• a: 12.535 ± 0.003 Å
• b: 13.116 ± 0.003 Å
• c: 13.785 ± 0.003 Å
• α: 82.52 ± 0.03°
• β: 77.7 ± 0.03°
• γ: 85.76 ± 0.03°
• Cell volume: 2193 ± 0.9 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.125
• Residual factor for significantly intense reflections: 0.0678
• Weighted residual factors for significantly intense reflections: 0.1629
• Weighted residual factors for all reflections included in the refinement: 0.1865
• Goodness-of-fit parameter for all reflections included in the refinement: 0.979
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No