Information card for entry 4317860

Structure parameters

• Chemical name: DIRECT ADDITION OF ALCOHOLS TO ORGANONITRILES ACTIVATED BY LIGATION TO A PLATINUM(IV) CENTER N.A.Bokash,V.Yu.Kukushkin,M.L.Kuznetsov,D.A.Garnovskii,G.Natile,A.J.L. Pombeiro
• Formula: C8 H18 Cl4 N2 O2 Pt
• Calculated formula: C8 H18 Cl4 N2 O2 Pt
• SMILES: C(C)(=[NH][Pt](Cl)(Cl)([NH]=C(C)OCC)(Cl)Cl)OCC
• Title of publication: Direct Addition of Alcohols to Organonitriles Activated by Ligation to a Platinum(IV) Center
• Authors of publication: Nadezhda A. Bokach; Vadim Yu. Kukushkin; Maxim L. Kuznetsov; Dmitrii A. Garnovskii; Giovanni Natile; Armando J. L. Pombeiro
• Journal of publication: Inorganic Chemistry
• Year of publication: 2002
• Journal volume: 41
• Pages of publication: 2041 - 2053
• a: 6.59 ± 0.001 Å
• b: 13.268 ± 0.003 Å
• c: 9.562 ± 0.002 Å
• α: 90°
• β: 103.72 ± 0.03°
• γ: 90°
• Cell volume: 812.2 ± 0.3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0239
• Residual factor for significantly intense reflections: 0.0239
• Weighted residual factors for significantly intense reflections: 0.0604
• Weighted residual factors for all reflections included in the refinement: 0.0604
• Goodness-of-fit parameter for all reflections included in the refinement: 1.036
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No